Theoretical study of photoinduced electron transfer from tetramethylethylene to tetracyanoethylene
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The Role of Electron Transfer and Charge Transfer in Organometallic Chemistry
The principal objective of this lecture is to describe the efficacy of organometals as electron donors, and to show how this property dominates many aspects of their chemistry. First, the structural effects of alkyl ligands (B) on the highest occupied molecular orbital (HOMO) of the neutral alkylmetals, R4Sn, R4Pb and R2Hg, are probed by photoelectron spectroscopy. The chemical properties of th...
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